Adsorption Isotherms, Freundlich Adsorption Isotherm, Limitations of Freundlich Isotherm (For CBSE, ICSE, IAS, NET, NRA 2022)

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Title: Adsorption Isotherms

What is Adsorption Isotherm?

  • Adsorption isotherms have been of immense importance to researches dealing with environmental protection and adsorption techniques. The two primary methods used for predicting the adsorption capacity of a given material are known as the Freundlich and Langmuir isotherms.
  • An adsorption isotherm is a graph that represents the variation in the amount of adsorbate (x) adsorbed on the surface of the adsorbent with the change in pressure at a constant temperature.
  • Adsorption Isotherm is a curve that expresses the variation in the amount of gas adsorbed by the adsorbent with pressure at constant temperature.
Adsorption Isotherm
  • As we know from Le Chatelier՚s principle, the direction of equilibrium in a reaction shifts in the direction in which stress is relieved. So, here we can see that upon application of excess pressure on the system, the equilibrium shifts in the direction where the number of molecules decreases so that the pressure in the system decreases.
  • From the graph, we also observe that after attaining a pressure Ps, that is the saturation pressure, the variation in the amount of adsorbent adhering to the adsorbate becomes zero. This happens because the surface area available for adsorption is limited and as all the sites are occupied, a further increase in pressure does not cause any difference.
  • Different adsorption isotherms have been proposed by different scientists namely,
    • Langmuir isotherm
    • Freundlich isotherm
    • BET theory
  • The graph shown above shows the isotherm proposed by Freundlich.

Freundlich Adsorption Isotherm

Freundlich adsorption gives the variation in the quantity of gas adsorbed by a unit mass of solid adsorbent with the change in pressure of the system for a given temperature. The expression for the Freundlich isotherm can be represented by the following equation:

where

Where is the mass of the gas adsorbed, is the mass of the adsorbent, is the pressure and is a constant which depends upon the nature of adsorbent and the gas at a given temperature. Taking the logarithm on both the sides of the equation, we get,

The plot of this equation is a straight line as represented by the following curve.

Freundlich Adsorption Isotherm

Freundlich Adsorption Isotherm

Limitations of Freundlich Isotherm

  • Freundlich isotherm only approximately explains the behaviour of adsorption. The value of can be between 0 and 1, therefore the equation holds good only over a limited range of pressure.
    • When is constant, the adsorption is independent of pressure.
    • When i.e.. . , , adsorption is directly proportional to pressure.
  • Experimental results support both of the above-mentioned conditions. At high pressure, the experimental isotherms always seem to approach saturation. Freundlich isotherm does not explain this observation and therefore, fails at high pressure.
  • The Freundlich isotherm was followed by two other isotherms – Langmuir adsorption isotherm and BET adsorption isotherm. Langmuir isotherm assumed that adsorption is monolayer in nature whereas BET isotherm assumed that it is multi-layer.

Langmuir Adsorption Isotherms

  • The Freundlich adsorption isotherm is followed by another two isotherms, Langmuir adsorption isotherms and BET theory. The Langmuir adsorption isotherms predict linear adsorption at low adsorption densities and a maximum surface coverage at higher solute metal concentrations.
  • The Langmuir adsorption isotherm has the form:

where

  • X is the weight of a solute sorbed by M grams of solid,
  • C is the equilibrium solute concentration,
  • a and b are constants equals the concentration when of the available adsorption sites.

The Langmuir adsorption is applicable for monolayer adsorption onto a homogeneous surface when no interaction occurs between adsorbed species.

BET Adsorption Isotherm

  • The theory of multilayer adsorption proposed by Brunauer, Emmett and Teller in 1938 (BET Theory) assumes that physisorption results in the formation of multilayer adsorption. The theory also assumes that the solid surface has uniform sites of adsorption and that adsorption at one site does not affect adsorption at neighbouring sites.
  • After the formation of the monolayer, the adsorption process can continue with the formation of multilayer involving the second layer, third layer and so on.
  • The equation for BET is

Applications of Adsorption

Following are the applications of adsorption:

  • Gas masks: Poisonous gases get adsorbed to at the surface of the mask and prevent its encounter when used by coal miners.
  • Production of vacuum: Traces of air are adsorbed on charcoal and removed from devices undergoing the process of evacuation.
  • Removal of moisture: Silica gel pellets are used for the adsorption of moisture in medicines and new plastic bottles in order to control humidity.
  • Removal of color: The juice extracted from cane is treated with animal charcoal for the removal of the coloring agent in order to get a clear liquid solution.
  • As Catalysts: Suitable materials are used as a catalyst such that reactants get adhered to its surface, thus enabling the reaction to proceed at a faster rate and increasing the rate of reaction.

Questions

What is the Purpose of Adsorption?

Answer: Adsorption is the adhesion from a gas, liquid or dissolved material to a layer of atoms, ions or molecules. This process creates an adsorbent film on the adsorbent՚s surface.

What is the Purpose of Isotherms?

Answer: Isotherm, a line drawn at the same temperature on a map or graph connecting points. Isotherms are commonly used in meteorology to view temperature distribution on the surface of the Earth or on a chart showing steady or constant pressure.

What Factors Affect Adsorption?

Answer: Adsorption factors include substratum temperature, pore-volume, degree of saturation, type of molecular sieve, type of adsorbent, and unique substratum surface area. At the top end, the width of a football pitch can be the surface area of 1 gm of the molecular sieve.

Does Adsorption Increase with Temperature?

Answer: Yes, with increased temperature, the adsorption potential increased. The adsorption ability of an adsorbent increases with temperature because the absorption of dye increases with the increase in temperature because dye molecules can obtain sufficient energy to interact with the active site on the substrate.

What is the Principle of Adsorption?

Answer: Adsorption is also the process of deposition of gas or liquid molecules on a solid surface. “Adsorption” is a well-established and effective technique for domestic and industrial effluent care. The most commonly used process of water treatment is “adsorption” to the activated carbon layer.

Why Are Adsorption Isotherms Important?

Answer:

The amount of dye adsorbed at the equilibrium time reflects the maximum adsorption capacity of the adsorbent under those operating conditions. Adsorption isotherm is basically important to describe how solutes interact with adsorbents and is critical in optimizing the use of adsorbents.

What Are Different Types of Adsorption Isotherm?

Answer:

Type I is characteristic of microporous solids with a relatively small proportion of the outer surface. Type II is to polymolecule adsorption in nonporous or microporous adsorbents. Type III is characteristic of non-porous sorbents with low energy of adsorbent-adsorbate interaction.

What is the Purpose of Isotherms?

Answer:

Isotherm, line drawn on a map or chart joining points with the same temperature. Isotherms are commonly used in meteorology to show the distribution of temperature at the Earth՚s surface or on a chart indicating constant level or constant pressure.

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