Chemistry Class-11: Chapter –6. Thermodynamics Part – 10

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V. Assertion and Reason Type

In the following questions a statement of Assertion (A) followed by a statement of Reason (R) is given. Choose the correct option out of the choices given below each question.

Question: 55

Assertion (A): Combustion of all organic compounds is an exothermic reaction.

Reason (R): The enthalpies of all elements in their standard state are zero.

(i) Both A and R are true and R is the correct explanation of A.

(ii) Both A and R are true but R is not the correct explanation of A.

(iii) A is true but R is false.

(iv) A is false but R is true.

Answer: (ii)

Question: 56

Assertion (A): Spontaneous process is an irreversible process and may be reversed by some external agency.

Reason (R): Decrease in enthalpy is a contributory factor for spontaneity.

(i) Both A and R are true and R is the correct explanation of A.

(ii) Both A and R are true but R is not the correct explanation of A.

(iii) A is true but R is false.

(iv) A is false but R is true.

Answer: (ii)

Question: 57

Assertion (A): A liquid crystallizes into a solid and is accompanied by decrease in entropy.

Reason (R): In crystals, molecules organize in an ordered manner.

(i) Both A and R are true and R is the correct explanation of A.

(ii) Both A and R are true but R is not the correct explanation of A.

(iii) A is true but R is false.

(iv) A is false but R is true.

Answer: (i)

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