Chemistry Class 11 NCERT Solutions: Chapter 12 Organic Chemistry Some Basic Principles and Techniques Part 10

Q: 17. Explain the terms Inductive and Electrometric effects. Which electron displacement effect explains the following correct orders of acidity of the carboxylic acids?

(A) Equation

(B) Equation

Answer:

Inductive effect

The permanent displacement of sigma Equation electrons along a saturated chain, whenever an electron withdrawing or electron-donating group is present, is called inductive effect. Inductive effect could be + I effect or – I effect. When an atom or group attracts electrons towards itself more strongly than hydrogen, it is said to possess – I effect. For example,

Equation

When an atom or group attracts electrons towards itself less strongly than hydrogen, it is said to possess + I effect. For example,

Equation

Electrometric effect

It involves the complete transfer of the shared pair of π electrons to either of the two atoms linked by multiple bonds in the presence of an attacking agent. For example,

Q 17 Structure of Electrometric Effect

Q 17 Structure of Electrometric Effect

Q 17 Structure of Electrometric Effect

Electrometric effect could be + E effect or – E effect.

+ E effect: When the electrons are transferred towards the attacking reagent

- E effect: When the electrons are transferred away from the attacking reagent

(A) Equation

The order of acidity can be explained on the basis of Inductive effect (– I effect). As the number of chlorine atoms increases, the – I effect increases. With the increase in – I effect, the acid strength also increases accordingly.

Q 17 A Structure of Acidic Strength

Q 17 a Structure of Acidic Strength

Q 17 A Structure of Acidic Strength

(B) Equation

The order of acidity can be explained on the basis of inductive effect (+ I effect). As the number of alkyl groups increases, the + I effect also increases. With the increase in + I effect, the acid strength also increases accordingly.

Q 17 B Structure of Acidic Strength

Q 17 B Structure of Acidic Strength

Q 17 B Structure of Acidic Strength

Q: 18. Give a brief description of the principles of the following techniques taking an example in each case.

(A) Crystallisation

(B) Distillation

(C) Chromatography

Answer:

(A) Crystallisation

Crystallisation is one of the most commonly used techniques for the purification of solid organic compounds.

Principle: It is based on the difference in the solubilities of the compound and the impurities in a given solvent. The impure compound gets dissolved in the solvent in which it is sparingly soluble at room temperature, but appreciably soluble at higher temperature. The solution is concentrated to obtain a nearly saturated solution. On cooling the solution, the pure compound crystallises out and is removed by filtration. For example, pure aspirin is obtained by recrystallising crude aspirin. Approximately, Equation of crude aspirin is dissolved in about 20 mL of ethyl alcohol. The solution is heated (if necessary) to ensure complete dissolution. The solution is then left undisturbed until some crystals start to separate out. The crystals are then filtered and dried.

(B) Distillation

This method is used to separate volatile liquids from non3volatile impurities or a mixture of those liquids that have a sufficient difference in their boiling points.

Principle: It is based on the fact that liquids having different boiling points vapourise at different temperatures. The vapours are then cooled and the liquids so formed are collected separately.

For example, a mixture of chloroform Equation and aniline Equation can be separated by the method of distillation. The mixture is taken in a round bottom flask fitted with a condenser. It is then heated. Chloroform, being more volatile, vaporizes first and passes into the condenser. In the condenser, the vapours condense and chloroform trickles down. In the round bottom flask, aniline is left behind.

(C) Chromatography

It is one of the most useful methods for the separation and purification of organic compounds.

Principle: It is based on the difference in movement of individual components of a mixture through the stationary phase under the influence of mobile phase. For example, a mixture of red and blue ink can be separated by chromatography. A drop of the mixture is placed on the chromatogram. The component of the ink, which is less adsorbed on the chromatogram, moves with the mobile phase while the less adsorbed component remains almost stationary.

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