Chemistry Class 12 NCERT Solutions: Chapter 12 Aldehydes Ketones and Carboxylic Acids Part 14

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Q: 20. Although phenoxide ion has more number of resonating structures than carboxylate ion, carboxylic acid is a stronger acid than phenol. Why?

Answer:

Resonance structures of phenoxide ion are:

Q 20 1 Resonance Structures of Phenoxide ion

Q 20 1 Resonance Structures of Phenoxide Ion

Q 20 1 Resonance Structures of Phenoxide ion

It can be observed from the resonance structures of phenoxide ion that in II, III and IV, less electronegative carbon atoms carry a negative charge. Therefore, these three structures contribute negligibly towards the resonance stability of the phenoxide ion. Hence, these structures can be eliminated. Only structures I and V carry a negative charge on the more electronegative oxygen atom.

Resonance structures of carboxylate ion are:

Q 20 2 Resonance Structures of Carboxylate ion

Q 20 2 Resonance Structures of Carboxylate Ion

Q 20 2 Resonance Structures of Carboxylate ion

In the case of carboxylate ion, resonating structures I’ and II’ contain a charge carried by a more electronegative oxygen atom.

Further, in resonating structures I’ and II’, the negative charge is delocalized over two oxygen atoms. But in resonating structures I and V of the phenoxide ion, the negative charge is localized on the same oxygen atom. Therefore, the resonating structures of carboxylate ion contribute more towards its stability than those of phenoxide ion. As a result, carboxylate ion is more resonance-stabilized than phenoxide ion. Hence, carboxylic acid is a stronger acid than phenol.