Chemistry Class 12 NCERT Solutions: Chapter 5 Surface-Chemistry Part 4 (For CBSE, ICSE, IAS, NET, NRA 2022)

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Q: 13. What are enzymes? Write in brief the mechanism of enzyme catalysis.

Answer:

Enzymes are basically protein molecules of high molecular masses. These form colloidal solutions when dissolved in water. These are complex, nitrogenous organic compounds produced by living plants and animals. Enzymes are also called ‘biochemical catalysts’ .

Q_13_Biiochemical Catalysts՚

Mechanism of enzyme catalysis:

On the surface of the enzymes, various cavities are present with characteristic shapes. These cavities possess active groups such as , etc. The reactant molecules having a complementary shape fit into the cavities just like a key fits into a lock. This leads to the formation of an activated complex. This complex then decomposes to give the product.

Hence,

Step 1:

(Activated complex)

Step 1:

Q: 14. How are colloids classified on the basis of

(i) Physical states of components

(ii) Nature of dispersion medium and

(iii) Interaction between dispersed phase and dispersion medium?

Answer:

Colloids can be classified on various bases:

(i) On the basis of the physical state of the components (by components we mean the dispersed phase and dispersion medium) . Depending on whether the components are solids, liquids, or gases, we can have eight types of colloids.

(ii) On the basis of the dispersion medium, sols can be divided as:

Q_14_The Basis of the Dispersion Medium, Sols Can be Divided
Dispersion MediumName of sol
WaterAquasol or hydrosol
AlcoholAlcosol
BenzeneBenzosol
GasesAerosol

(iii) On the basis of the nature of the interaction between the dispersed phase and dispersion medium, the colloids can be classified as lyophilic (solvent attracting) and lyophobic (solvent repelling) .

Q: 15. Explain what is observed

(i) When a beam of light is passed through a colloidal sol.

(ii) An electrolyte, NaCl is added to hydrated ferric oxide sol.

(iii) Electric current is passed through a colloidal sol?

Answer:

(i) When a beam of light is passed through a colloidal solution, then scattering of light is observed. This is known as the Tyndall effect. This scattering of light illuminates the path of the beam in the colloidal solution.

(ii) When is added to ferric oxide sol, it dissociates to give and ions. Particles of ferric oxide sol are positively charged. Thus, they get coagulated in the presence of negatively charged ions.

(iii) The colloidal particles are charged and carry either a positive or negative charge. The dispersion medium carries an equal and opposite charge. This makes the whole system neutral. Under the influence of an electric current, the colloidal particles move towards the oppositely charged electrode. When they come in contact with the electrode, they lose their charge and coagulate.

Q: 16. What are emulsions? What are their different types? Give example of each type.

Answer:

The colloidal solution in which both the dispersed phase and dispersion medium are liquids is called an emulsion.

There are two types of emulsions:

(A) Oil in water type:

Here, oil is the dispersed phase while water is the dispersion medium. For example: milk, vanishing cream, etc.

(B) Water in oil type:

Here, water is the dispersed phase while oil is the dispersion medium. For example: cold cream, butter, etc.

Q: 17. What is demulsification? Name two demulsifiers.

Answer

The process of decomposition of an emulsion into its constituent liquids is called demulsification. Examples of demulsifiers are surfactants, ethylene oxide, etc.

Q: 18. Action of soap is due to emulsification and micelle formation. Comment.

Answer

The cleansing action of soap is due to emulsification and micelle formation. Soaps are basically sodium and potassium salts of long chain fatty acids, The end of the molecule to which the sodium is attached is polar in nature, while the alkyl-end is non-polar. Thus, a soap molecule contains a hydrophilic (polar) and a hydrophobic (non- polar) part.

When soap is added to water containing dirt, the soap molecules surround the dirt particles in such a manner that their hydrophobic parts get attached to the dirt molecule and the hydrophilic parts point away from the dirt molecule. This is known as micelle formation. Thus, we can say that the polar group dissolves in water while the non-polar group dissolves in the dirt particle. Now, as these micelles are negatively charged, they do not coalesce and a stable emulsion is formed.

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